Absolute oscillator strengths from K-shell electron-energy-loss spectra of the fluoroethenes and 1,3-perfluorobutadiene

Absolute oscillator strengths in the region of carbon and fluorine K-shell excitation have been derived for CH2CH2, CH2CHF, cis-CHFCHF, CH2CF2, CHFCF2, CF2CF2, 1,3-C4H6, and 1,3-C4F6 from electron-energy-loss spectra recorded under dipole-dominated conditions. The methods used to derive absolute oscillator strengths from relative energy-loss intensities are discussed in detail. The accuracy of the procedures is tested through comparisons with …