Interaction energies in nematic liquid crystal suspensions
Abstract
We establish, as $\rho\to 0$, an asymptotic expansion for the minimal
Dirichlet energy of $\mathbb S^2$-valued maps outside a finite number of
three-dimensional particles of size $\rho$ with fixed centers
$x_j\in\mathbb{R}^3$, under general anchoring conditions at the particle
boundaries. Up to a scaling factor, this expansion is of the form
\begin{align*} E_\rho = \sum_j \mu_j -4\pi\rho \sum_{i\neq j} \frac{\langle
v_i,v_j\rangle}{|x_i-x_j|} +o(\rho)\,, \end{align*} where $\mu_j$ is the
minimal energy after zooming in at scale $\rho$ around each particle, and
$v_j\in\mathbb{R}^3$ is a torque determined by the far-field behavior of the
corresponding single-particle minimizer. The above expansion highlights
Coulomb-like interactions between the particle centers. This agrees with the
\textit{electrostatics analogy} commonly used in the physics literature for
colloid interactions in nematic liquid crystal. That analogy was pioneered by
Brochard and de Gennes in 1970, based on a formal linearization argument. We
obtain here for the first time a precise estimate of the energy error
introduced by this linearization procedure.