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Mass-Preserving Modeling of Diffusion in a Closed...
Journal article

Mass-Preserving Modeling of Diffusion in a Closed System

Abstract

With zero-flux boundary conditions imposed at both ends, amounts of components in a system cannot change as a result of a unidimensional diffusion in it. With appropriately chosen time steps, the Crank-Nicolson scheme can dependably track a temporal evolution of an initial discrete concentration profile, but an invariance of an area below a continuously changing concentration vs. position curve is not guaranteed. In this work, a heuristic yet mathematically sound technique of incorporating a "constant integral" requirement into the Crank-Nicolson method is proposed.

Authors

Malakhov DV

Journal

Journal of Phase Equilibria and Diffusion, Vol. 46, No. 1, pp. 31–48

Publisher

Springer Nature

Publication Date

February 1, 2025

DOI

10.1007/s11669-025-01174-7

ISSN

1547-7037

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