Journal article
Bis(2-Amino-5-bromopyrimidinium) Tetrahalometallates: Crystal structures of (2-amino-5-bromopyrimidinium)2 MCl4 (M = Co, Zn)
Abstract
The reactions of metal(II) chlorides and bromides with 2-amino-5-bromopyrimidine (2-abpm) in neutral and acidic solution were investigated. The reaction with ZnCl2, ZnBr2, CoCl2, CoBr2 and MnCl2 in acidic nitromethane solution gave complexes of the formula (2-abpmH)2MX4 (1, M = Zn, X = Cl; 2, M = Zn, X = Br; 3, M = Co, X = Cl; 4, M = Co, X = Br; 5, M = Mn, X = Cl). Crystals of 1 and 3 suitable for single crystal X-ray diffraction were obtained. …
Authors
Andrews S; Corwin J; Landry B; Martin M; Parnass K; Suen A; Turnbull MM; Schneider RT; Landee CP; Awwadi FF
Journal
Journal of Coordination Chemistry, Vol. 59, No. 13, pp. 1451–1465
Publisher
Taylor & Francis
Publication Date
September 10, 2006
DOI
10.1080/00958970600559385
ISSN
0095-8972