A highly sensitive ion-selective chemiresistive sensor for online monitoring of lead ions in water

Dissolved lead is a serious but common health hazard in drinking water, yet there is still no practical way to monitor its levels continuously in the distribution system or at the point of use. Here we propose using a lead-selective membrane on top of a chemiresistive device to continuously measure Pb²⁺ ion concentrations in real time. The detection limit was lowered by stabilizing the surface of the resistive film with sodium hydroxide and 15-crown-5 ether and optimizing the sensor geometry to maximize the effective surface area. The detection mechanism is based on the complexation of the Pb²⁺ ions by the lead ionophores within the membrane, thus modulating the interactions between the ionophores and the chemiresistive film. The limit of detection of the fabricated devices was reliably below 2 μg L^-1, with concentrations up to 3 mg L^-1 routinely quantifiable over several measurement cycles. The chemiresistive sensors can thus achieve lower detection limits than potentiometric devices while being more robust and simpler to fabricate by omitting the reference electrode. Ion-selective membrane-covered chemiresistors can therefore be deployed to continuously monitor drinking water sources and detect harmful levels of lead in real time.