ChemInform Abstract: Cyclic Nitronates from the Diastereoselective Addition of 1‐Trimethylsilyloxycyclohexene to Nitroolefins. Starting Materials for Stereoselective Henry Reactions and 1,3‐Dipolar Cycloadditions. Journal Articles uri icon

  •  
  • Overview
  •  
  • Research
  •  
  • Identity
  •  
  • Additional Document Info
  •  
  • View All
  •  

abstract

  • AbstractThe Ti‐induced combination of the cyclohexene (I) with the E‐nitroolefins (II) yielding the separable prim. products (III)‐(V) proceeds preferentially with relative topicity ul, opposite to the corresponding reaction of enolates or enamines.

publication date

  • September 29, 1987