ChemInform Abstract: He I Photoelectron Spectra of the Unstable Substituted Aminoboranes, Aminodifluoro‐, Aminodichloro‐, and Aminodibromoborane. An Experimental and Theoretical Study. Journal Articles uri icon

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abstract

  • AbstractHigh yield routes to H2NBF2, H2NBCl2, and H2NBBr2 (via dehydrohalogenation of H3N·BF3 and H3N·BCl3 and a NH3/BBr3 gas‐phase mixture by use of on‐line He(I) photoelectron spectroscopy) have been demonstrated, and the identities and orbital assignments have been established by a comparison with methyl‐substituted analogues and the isoelectronic ethylenes.

publication date

  • August 18, 1987