ChemInform Abstract: Gaseous “H3PS2” ‐ Generation and Characterization. Journal Articles uri icon

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abstract

  • AbstractCollisional activation (CA) mass spectra and thermochemical data show that the alkene elimination from the dialkyldithiophosphinic acids (I) leads to a mixture of the tautomeric radical cations (II) and (III) containing tri‐ or dicoordinated phosphorus, whereas tetracoordinated phosphorus corresponding to the ionized dithiophosphinic acid H2P(S)SH is not observed.

publication date

  • June 5, 1990