ChemInform Abstract: X‐Ray Crystal Structures of [XeF][MF6] (M: As, Sb, Bi), [XeF][M2F11] (M: Sb, Bi) and Estimated Thermochemical Data and Predicted Stabilities for Noble‐Gas Fluorocation Salts Using Volume‐Based Thermodynamics.

Abstract The crystal structures of [XeF][SbF 6 ] (space group P2 1 /c, Z = 4), [XeF][BiF 6 ] (space group P2 1 /c, Z = 4), and [XeF][Bi 2 F 11 ] (space group P2 1 2 1 2 1 , Z = 4) are determined for the first time (single crystal XRD), and those of XeF 2 (space group I4/mmm, Z = 2), [XeF][AsF 6 ] (space group P2 1 /n, Z = 4), [XeF][Sb 2 F 11 ] (space group P2 1 , Z = 2), and [XeF 3 ][Sb 2 F 11 ] (space group P $\bar 1$ , Z = 2) are redetermined with greater precision at ‐173 °C.