ChemInform Abstract: X‐Ray Crystal Structures of [XeF][MF6] (M: As, Sb, Bi), [XeF][M2F11] (M: Sb, Bi) and Estimated Thermochemical Data and Predicted Stabilities for Noble‐Gas Fluorocation Salts Using Volume‐Based Thermodynamics.
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AbstractThe crystal structures of [XeF][SbF6] (space group P21/c, Z = 4), [XeF][BiF6] (space group P21/c, Z = 4), and [XeF][Bi2F11] (space group P212121, Z = 4) are determined for the first time (single crystal XRD), and those of XeF2 (space group I4/mmm, Z = 2), [XeF][AsF6] (space group P21/n, Z = 4), [XeF][Sb2F11] (space group P21, Z = 2), and [XeF3][Sb2F11] (space group P$\bar 1$, Z = 2) are redetermined with greater precision at ‐173 °C.
