Cooperative strings and glassy dynamics in various confined geometries
Abstract
Previously, we developed a minimal model based on random cooperative strings
for the relaxation of supercooled liquids in the bulk and near free interfaces,
and we recovered some key experimental observations. In this article, after
recalling the main ingredients of the cooperative string model, we study the
effective glass transition and surface mobility of various
experimentally-relevant confined geometries: freestanding films, supported
films, spherical particles, and cylindrical particles, with free interfaces
and/or passive substrates. Finally, we introduce a novel way to account for a
purely attractive substrate, and explore the impact of the latter in the
previous geometries.