Sharp interface limit of an energy modelling nanoparticle-polymer blends
Abstract
We identify the $\Gamma$-limit of a nanoparticle-polymer model as the number
of particles goes to infinity and as the size of the particles and the phase
transition thickness of the polymer phases approach zero. The limiting energy
consists of two terms: the perimeter of the interface separating the phases and
a penalization term related to the density distribution of the infinitely many
small nanoparticles. We prove that local minimizers of the limiting energy
admit regular phase boundaries and derive necessary conditions of local
minimality via the first variation. Finally we discuss possible critical and
minimizing patterns in two dimensions and how these patterns vary from global
minimizers of the purely local isoperimetric problem.