Mechanical Deformation of Nanoscale Metal Rods: When size and shape matters

Understanding nanomechanical response of materials represents a scientific challenge. Here, we have used in-situ electron microscopy to reveal drastic for the first time changes of structural behavior during deformation of 1-nm-wide metal rods as a function of temperature. At 300 K, stretched nanowires stay defect-free, while at 150 K, elongation is associated with planar defects. As size is reduced, energy barriers become so small that ambient thermal energy is sufficient to overcome them. Nanorods display an elastic regime until a mechanism with high enough blocking barrier can be nucleated. Ab-initio calculations revealed that contribution from surface steps overrule stacking fault energetics in nanorods, in such a way that system size and shape determines preferred fault gliding directions. This induces anisotropic behavior and, even large differences in elastic or plastic response for elongation or compression. These results provide a new framework to improve theoretical models and atomic potentials to describe the mechanical properties at nanoscale.