Film Thickness Dependent Stability and Glass Transition Temperature of Polymer Films Produced by Physical Vapor Deposition

We report measurements of the onset temperature of rejuvenation, T_{onset}, and the fictive temperature, T_{f}, for ultrathin stable polystyrene with thicknesses from 10 to 50 nm prepared by physical vapor deposition. We also measure the T_{g} of these glasses on the first cooling after rejuvenation as well as the density anomaly of the as-deposited material. Both the T_{g} in rejuvenated films and the T_{onset} in stable films decrease with …