NMR Studies of Sulfonamide Based Deep Eutectic Lithium Electrolytes

LiPF 6 solutions in organic carbonates, the present day battery industry state of the art lithium ion battery (LIBs) electrolytes, while providing adequate performance in LIBs for consumer applications, have some well-known and considerable drawbacks. LiPF 6 hydrolyzes with HF formation and decomposes thermally at near-ambient temperatures, linear carbonates have high flammability and also generate flammable gases through their decomposition. Their replacement or materials-level mitigation measures for their deficiencies should target improved battery performance at both low and high temperatures, as well as increased battery durability. Ionic liquids (ILs) have been at the forefront of the search for improved LIB electrolytes. However; many ILs are very expensive and often exhibit specific conductivities lower by more than one order of magnitude compared to LiPF 6 in organic carbonates even at room temperature. Deep eutectic electrolytes 1 (characterized by a significant depression in the freezing point for a mixture of two or more compounds at some composition) provide a much lower cost alternative to IL’s, while matching their low flammability. Our work focuses on the sulfonamide - lithium class binary deep eutectic electrolytes. 2 Besides discussing some of the physical properties which determine their suitability for LIBs (electrochemical window, conductivity, viscosity), we hereby present their detailed characterization by NMR. Such a study is particularly important for an in-depth understanding of their structure and properties, which should guide ongoing efforts towards improving their properties. Specialized NMR techniques can provide insight into both the transport properties and the local environment of these deep eutectic electrolytes. In particular, diffusion ordered spectroscopy (DOSY) 3 can yield information on the diffusion coefficients and transference numbers of relevant nuclei in the sulfonamide component, cation and anion, i.e., 1 H, 7 Li, and 19 F. We will show that NMR can provide diffusion coefficients over several orders of magnitude (Figure 1). Lithium transport numbers greater than 0.5 have been observed and are hereby reported. Changes in these parameters under applied electric potential are investigated through in-situ NMR imaging techniques, whose efficacy has been demonstrated previously. 4 In particular, in situ 7 Li imaging can map out the both spatial and temporal dependences of concentration gradients that develop in an electrochemical cells under an applied potential. Such data can then be used to obtain diffusion coefficients and transference numbers from a mathematical solution of the inverse transport problem for the system under study. 5 To further probe the solvent structure surrounding the lithium cations, we utilized 1 H- 7 Li and 19 F- 7 Li heteronuclear Overhauser effect spectroscopy (HOESY). 6 Our NMR results will be compared with those from molecular dynamics simulations. References [1] Q. Zhang, K. D. O. Vigier, S. Royer, and F. Jérôme, Chem. Soc. Rev. 41 , 7108 (2012) [2] I. C. Halalay, D. R. Frisch, O.E. Geiculescu, D. D. Desmarteau, S. E. Creager, and C. Lu, disclosure US 2011/0111308 [3] E. O. Stejskal & J. E. Tanner, J. Chem. Phys. 42 , 288 (1965). [4] S. A. Krachkovskiy, A. D. Pauric, I. C. Halalay, and G. R. Goward, J. Phys. Chem. Lett. 4 , 3940 (2013). [5] Nyman, A.; Behm, M.; Lindbergh, G. Electrochim. Acta 2008, 53 (22), 6356-6365. [6] W. Bauer, Magn. Reson. Chem. 34 , 532 (1996). Acknowledgements The authors acknowledge funding through the NSERC APC program and GM of Canada.