Organo-scandium and -yttrium complexes supported...

Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

Abstract

Reaction of a salicylaldiminato ligand with M(CH2SiMe2Ph)3(THF)2 (M = Sc, Y) leads to diastereoselective formation of highly thermally stable L2MR complexes whose reactivity with dihydrogen to form Group 3 metal hydrides is described.

Authors

Emslie DJH; Piers WE; MacDonald R

Journal

Dalton Transactions, Vol. 0, No. 3, pp. 293–294

Publisher

Royal Society of Chemistry (RSC)

Publication Date

January 23, 2002

DOI

10.1039/b108336h

ISSN

1477-9226

Associated Experts

David James Hannington Emslie

Professor, Faculty of Science

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Labels

Fields of Research (FoR)

3402 Inorganic chemistry 34 Chemical Sciences

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