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Development of a one-pot method for the...
Journal article

Development of a one-pot method for the homologation of aldehydes to carboxylic acids

Abstract

A highly efficient method is described for the one-carbon homologation of aldehydes to carboxylic acid derivatives employing the reaction of a 1,1-bis-dimethylphosphonate derivative with the aldehyde and controlled acid hydrolysis of the derived α-phosphonoenamine intermediate.

Authors

McNulty J; Das P

Journal

Tetrahedron, Vol. 65, No. 37, pp. 7794–7800

Publisher

Elsevier

Publication Date

September 2009

DOI

10.1016/j.tet.2009.07.032

ISSN

0040-4020