P‐Phenyl‐2,2,6,6‐tetramethylphosphorinan‐4‐ol: An Air‐Stable P,O‐Type Ligand for Palladium‐Mediated Cross‐Coupling Reactions

Abstract A two‐step entry to a chemically robust, hindered P,O‐type phosphorinane‐based ligand and its application toward Pd‐mediated cross‐coupling reactions of unactivated aryl chlorides is presented.