Stereoselective Wittig olefination reactions...

Stereoselective Wittig olefination reactions employing a novel ortho-P-aryl alkoxide effect

Abstract

Non-stabilized ortho-P-alkoxy-substituted ylides react with aromatic and aliphatic aldehydes providing (E)-olefins with high stereocontrol, also allowing easy phosphine oxide removal in certain cases.

Authors

McNulty J; Keskar K

Journal

Tetrahedron Letters, Vol. 49, No. 49, pp. 7054–7057

Publisher

Elsevier

Publication Date

December 1, 2008

DOI

10.1016/j.tetlet.2008.09.150

ISSN

0040-4039

Associated Experts

James Mcnulty

Professor, Faculty of Science

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Labels

Fields of Research (FoR)

3402 Inorganic Chemistry 3405 Organic chemistry 34 Chemical Sciences 3101 Biochemistry and cell biology 3404 Medicinal and biomolecular chemistry

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