Photochemical isomerization of a C 2 N 4 S 2 ring...

Photochemical isomerization of a C 2 N 4 S 2 ring into a diazene

Abstract

The eight-membered rings (ArC)2N4(SPh)2[Ar = 4-XC6H4(X = Br, CF3)] undergo photoisomerization to the purple diazenes PhSNC(Ar)NNC(Ar)NSPh by a first-order process that is thermally smmetry-forbidden, but photochemically allowed.

Authors

Chivers T; Vargas-Baca I; Ziegler T; Zoricak P

Journal

Chemical Communications, Vol. 0, No. 8, pp. 949–950

Publisher

Royal Society of Chemistry (RSC)

Publication Date

January 1, 1996

DOI

10.1039/cc9960000949

ISSN

1359-7345

Associated Experts

Ignacio Vargas-baca

Professor, Faculty of Science

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Labels

Fields of Research (FoR)

3402 Inorganic Chemistry 34 Chemical sciences 3406 Physical Chemistry 3407 Theoretical and Computational Chemistry 40 Engineering

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