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Stability of Ordered Phases in Weakly Segregated...
Journal article

Stability of Ordered Phases in Weakly Segregated Diblock Copolymer Systems

Abstract

Stability of ordered phases in diblock copolymer melts is studied using a theory of anisotropic fluctuations, which bears a useful similarity with energy band theory in solids. We calculated stability lines of all ordered phases and found the hexagonally perforated lamellar phase to be unstable around the lamellar-cylindrical (LC) phase boundaries. We used fluctuation analysis to obtain dynamical pathways between ordered phases and argue that …

Authors

Laradji M; Shi A-C; Desai RC; Noolandi J

Journal

Physical Review Letters, Vol. 78, No. 13, pp. 2577–2580

Publisher

American Physical Society (APS)

Publication Date

March 31, 1997

DOI

10.1103/physrevlett.78.2577

ISSN

0031-9007