Rhodium(ii) dimers without metal–metal bonds Academic Article uri icon

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abstract

  • Oxidation of (MeBDI)Rh(cyclooctene) (MeBDI = [2,6-Me2C6H3NCMe]2CH) with Br2 or I2 produces paramagnetic halide-bridged RhII dimers [(MeBDI)Rh]2(μ-X)2 without a direct Rh–Rh bond.

publication date

  • August 14, 2015