Journal article
A Homoleptic Copper(II)−Thiocyanato Linear Chain
Abstract
Under conditions of excess Cu(II) ions, it is possible to synthesize a novel tetraphenylarsonium copper(II) thiocyanato anion salt, possessing the stoichiometry [AsPh4][Cu(SCN)3] 1. Furthermore, the crystal structure of 1 revealed the complex salt to be a rare example of a metal−thiocyanato one-dimensional chain compound, containing equatorial−equatorial copper−thiocyanato bridges. Crystal structure data (297 K) are monoclinic, P2(1)/c, a = …
Authors
White CA; Yap GPA; Raju NP; Greedan JE; Crutchley RJ
Journal
Inorganic Chemistry, Vol. 38, No. 11, pp. 2548–2549
Publisher
American Chemical Society (ACS)
Publication Date
May 1, 1999
DOI
10.1021/ic990083o
ISSN
0020-1669