Acid catalysed stereomutations about the C(2)–C(3)...

Acid catalysed stereomutations about the C(2)–C(3) bond of 3-aryl-1-methoxyallyl cations. Dication formation by oxygen protonation

Abstract

The thermally induced cis to trans isomerization of 3-aryl-1-methoxyallyl cations in superacid media is shown to occur by formation of an intermediate O-protonated dication.

Authors

Blackburn C; Childs RF

Journal

Chemical Communications, Vol. 0, No. 13, pp. 812–813

Publisher

Royal Society of Chemistry (RSC)

Publication Date

January 1, 1984

DOI

10.1039/c39840000812

ISSN

1359-7345

Associated Experts

Ronald Frank Childs

Professor Emeritus, Faculty of Science

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Labels

Fields of Research (FoR)

3402 Inorganic Chemistry 34 Chemical sciences 3407 Theoretical and Computational Chemistry 40 Engineering

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