A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2rings Academic Article uri icon

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abstract

  • Oxidation of alkali metal derivatives of [Te((t)BuN)P(μ-N(t)Bu)(2)P(N(t)Bu)Te](2-) with I(2) produces the intermediate ditelluride dianion [Te((t)BuN)P(μ-N(t)Bu)(2)P(N(t)Bu)Te](2)(2-) with a planar PTeTeP conformation and, subsequently, the cyclic tritelluride [((t)BuN)P(μ-N(t)Bu)(2)P(N(t)Bu)(μ-TeTeTe)].

authors

  • Nordheider, Andreas
  • Chivers, Tristram
  • Thirumoorthi, Ramalingam
  • Athukorala Arachchige, Kasun S
  • Slawin, Alexandra MZ
  • Woollins, J Derek
  • Vargas-baca, Ignacio

publication date

  • March 14, 2013