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125I‑Tetrazines and Inverse-Electron-Demand...
Journal article

125I‑Tetrazines and Inverse-Electron-Demand Diels–Alder Chemistry: A Convenient Radioiodination Strategy for Biomolecule Labeling, Screening, and Biodistribution Studies

Abstract

A convenient method to prepare radioiodinated tetrazines was developed, such that a bioorthogonal inverse electron demand Diels-Alder reaction can be used to label biomolecules with iodine-125 for in vitro screening and in vivo biodistribution studies. The tetrazine was prepared by employing a high-yielding oxidative halo destannylation reaction that concomitantly oxidized the dihydrotetrazine precursor. The product reacts quickly and …

Authors

Albu SA; Al-Karmi SA; Vito A; Dzandzi JPK; Zlitni A; Beckford-Vera D; Blacker M; Janzen N; Patel RM; Capretta A

Journal

Bioconjugate Chemistry, Vol. 27, No. 1, pp. 207–216

Publisher

American Chemical Society (ACS)

Publication Date

January 20, 2016

DOI

10.1021/acs.bioconjchem.5b00609

ISSN

1043-1802