Uranium(iv) alkyl cations: synthesis, structures, comparison with thorium(iv) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity Journal Articles uri icon

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abstract

  • Uranium(iv) alkyl cations have been prepared, and arene solvent coordination was shown to have a major impact on ethylene polymerization activity. Actinide-arene binding was studied experimentally in the solid state and solution, and computationally.

publication date

  • November 30, 2022