Computational study of the thermal rearrangement of acetoxy(methoxy)carbene Journal Articles

abstract

• AbstractThermolysis of 2‐acetoxy‐2‐methoxy‐5,5‐dimethyl‐Δ3‐1,3,4‐oxadiazoline affords acetoxy(methoxy)carbene. Thermal rearrangement of acetoxy(methoxy)carbene to methyl pyruvate is a concerted 1,2‐migration, avoiding a potential radical‐pair mechanism. Copyright © 2005 John Wiley & Sons, Ltd.

authors

• Czardybon, Wojciech
• Warkentin, John
• Werstiuk, Nick Henry

status

• published 

publication date

• June 2005

has subject area

• 0305 Organic Chemistry (FoR)
• 0306 Physical Chemistry (incl. Structural) (FoR)
• 0307 Theoretical and Computational Chemistry (FoR)
• Organic Chemistry (Science Metrix)

published in

• Journal of Physical Organic Chemistry  Journal

keywords

• ALKYLACETOXYCARBENES
• Chemistry
• Chemistry, Organic
• Chemistry, Physical
• GENERATION
• Physical Sciences
• Science & Technology
• acetoxy(methoxy)carbene
• carbene
• computation
• concerted
• rearrangement

Digital Object Identifier (DOI)

• 10.1002/poc.899

start page

• 486

end page

• 490

volume

• 18

issue

• 6