Journal article
Mixed metal acylium clusters: A chemical and spectroscopic study
Abstract
The generation of mixed metal acylium cations [MCo2(CO)6CCO]+, M = (C5H5Mo(CO)2, (C5Me5)Mo(CO)2 and (C5H5, from the parent esters via treatment with HPF6 in propionic anhydride is described. These cations and also the related [(C5H5)2Co3(CO)4CCO]+ cluster react with alcohols to give esters and with indole or pyrrole to give Friedel-Crafts type products. 1H NMR, IR and FAB mass spectroscopic data are reported.
Authors
D'Agostino MF; Mlekuz M; McGlinchey MJ
Journal
Journal of Organometallic Chemistry, Vol. 345, No. 3, pp. 371–382
Publisher
Elsevier
Publication Date
5 1988
DOI
10.1016/0022-328x(88)80100-1
ISSN
0022-328X