Journal article
The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4R)] complexes
Abstract
[Co(η4-C4Ph4)(η5-C5H4R)] (R=CO2Me, 2; and CHO, 3), prepared by the reactions of [Co(η5-C5H4R)(PPh3)2] with Ph2C2, were used as precursors for complexes where R=CH2OH, 4; CH2Cl, 5; CH2P(O)(OEt)2, 6; CH2PPh3 +, [7]+; C(O)Fc, 8 (Fc=ferrocenyl); CFc2OH, 9; CHC(CN)2, 10; syn and anti-CHNNH–C6H3(NO2)2-2,4, 11; CH(Fc)OH, 12; CHFc+, [13]+; and CFc2 +, [14]+. Most new compounds have been characterised by elemental analyses, and all by spectroscopy. …
Authors
O’Donohue P; McAdam CJ; Courtney D; Ortin Y; Müller-Bunz H; Manning AR; McGlinchey MJ; Simpson J
Journal
Journal of Organometallic Chemistry, Vol. 696, No. 8, pp. 1496–1509
Publisher
Elsevier
Publication Date
4 2011
DOI
10.1016/j.jorganchem.2010.12.026
ISSN
0022-328X