Journal article
Stilbene analogues incorporating the Co(η4-C4Ph4)(η5-C5H4-) end group
Abstract
A number of organometallic stilbenes of the general type [Co(η4-C4Ph4)(η5-C5H4CHCHR] are reported where R is C6H4X-4 (X = H, OMe, Br, NO2), 1-naphthyl, 9-anthryl, 1-pyrenyl, (η5-C5H4)Co(η4-C4Ph4), and (η5-C5H4)Fe(η5-C5H4Y) {Y=CHO, CHC(CN)2 and CHCHC5H4-η5)Co(η4-C4Ph4)}. They were prepared by Wittig or Horner–Wadsworth–Emmons reactions which yield both E and Z or only E products respectively. The isomers were separated and all compounds …
Authors
O’Donohue P; McAdam CJ; Courtney D; Ortin Y; Müller-Bunz H; Manning AR; McGlinchey MJ; Simpson J
Journal
Journal of Organometallic Chemistry, Vol. 696, No. 8, pp. 1510–1527
Publisher
Elsevier
Publication Date
April 2011
DOI
10.1016/j.jorganchem.2011.01.017
ISSN
0022-328X