Journal article
Crystal Structure and Physical Properties of a New CuTi2S4 Modification in Comparison to the Thiospinel
Abstract
A new modification of CuTi(2)S(4) was prepared from the elements at 425 degrees C. It crystallizes in the rhombohedral space group Rm, with lattice parameters of a = 7.0242(4) A, c = 34.834(4) A, and V = 1488.4(2) A(3) (Z = 12). Two topologically different interlayer regions exist between the close-packed S layers that alternate along the c axis: one comprises both Cu (in tetrahedral voids) and Ti atoms (in octahedral voids), and the second …
Authors
Soheilnia N; Kleinke KM; Dashjav E; Cuthbert HL; Greedan JE; Kleinke H
Journal
Inorganic Chemistry, Vol. 43, No. 20, pp. 6473–6478
Publisher
American Chemical Society (ACS)
Publication Date
October 1, 2004
DOI
10.1021/ic0495113
ISSN
0020-1669