Dynamic equilibration of η1-carbene and η2-alkyne moieties within an alkynylcarbene dimanganese complex Journal Articles uri icon

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abstract

  • The coordination of an additional [Cp(CO)2Mn] fragment to the alkyne linkage of an alkynylcarbene complex of the type Cp(CO)2Mn=C(R')C identical to CR" yields a highly fluxional molecule, in which the [eta 1-carbene] and [eta 2-alkyne] moieties are seen to exchange rapidly on the NMR time scale.

publication date

  • 2001