Are the compressive effects of encapsulation an...

Are the compressive effects of encapsulation an artifact of the bond valence parameters?

Abstract

Abstract The large bond valence sums found for O 2– en-capsulated by Pb 2+ ions are shown to result from the use of inappropriate bond valence parameters. New values of r o = 1.963 Å and b = 0.49 Å are recommended for Pb 2+ -O bonds.

Authors

Krivovichev SV; Brown ID

Journal

Zeitschrift für Kristallographie - Crystalline Materials, Vol. 216, No. 5, pp. 245–247

Publisher

De Gruyter

Publication Date

May 1, 2001

DOI

10.1524/zkri.216.5.245.20378

ISSN

2194-4946

Associated Experts

Ian David Brown

Professor Emeritus, Faculty of Science

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Labels

Fields of Research (FoR)

3402 Inorganic chemistry 34 Chemical Sciences 3403 Macromolecular and materials chemistry

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