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Infrared-active phonons in RTiO3 perovskites...
Journal article

Infrared-active phonons in RTiO3 perovskites (R=La,Ce,Pr,Nd,Sm,Gd)

Abstract

The room-temperature reflectance (100–1000 cm-1) of the rare-earth titanites (RTiO3 R=La,Ce,Pr,Nd,Sm,Gd) has been measured. The spectrum for LaTiO3, CeTiO3, and PrTiO3 consists of the three main perovskite vibrational bands. The central band, near 340 cm-1, consists of several barely resolved modes which begin to separate in NdTiO3 and SmTiO3 and which split into two clusters of modes in GdTiO3. These features are correlated with an increasing …

Authors

Crandles DA; Timusk T; Garrett JD; Greedan JE

Journal

Physical Review B, Vol. 49, No. 6, pp. 4299–4302

Publisher

American Physical Society (APS)

Publication Date

February 1, 1994

DOI

10.1103/physrevb.49.4299

ISSN

2469-9950