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Are covalent bonds really directed?
Journal article

Are covalent bonds really directed?

Abstract

The flux theory of the chemical bond, which provides a physical description of chemical structure based on classical electrostatic theory, correctly predicts the angles between bonds, to the extent that they depend on the intrinsic properties of the bonded atoms. It is based on the justifiable assumption that the charge density around the nucleus of an atom retains most of its spherical symmetry even when bonded. A knowledge of these intrinsic bond angles permits the measurement and analysis of the steric angular strains that result from the mapping of the bond network into three-dimensional space. The work ends by pointing out that there are better ways of characterizing bonds than describing them as covalent or ionic.

Authors

Brown ID

Journal

American Mineralogist, Vol. 101, No. 3, pp. 531–539

Publisher

Mineralogical Society of America

Publication Date

March 1, 2016

DOI

10.2138/am-2016-5299

ISSN

0003-004X

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