X-ray-absorption edge shifts in rare-earth–transition-metal compounds

X-ray-absorption K-edge shifts of cobalt have been measured in Y2Co17, YCo5, and YCo3 compounds whose crystal structures are derivatives of the CaCu5 structure. The edge shifts vary monotonically with the Y:Co ratio. We compare them with Fe, Y, and Ce edge shifts determined for several other related materials, including Y2Fe17, Ce2Fe17, and CeCo2. In all cases, the shifts are the same sign, a fact that points to the absence of a significant uncompensated charge transfer from one elemental constituent to another. Identifying the edge shifts as core-level shifts, we find that the Watson-Hudis-Perlman charge-compensation model is applicable to these systems; estimates of the model parameters lead to small net charge transfers consistent with available Mössbauer effect measurements. Our results show that there is no straightforward relation between the transition-metal magnetic moment and either charge transfer or corresponding absorption edge shift, which implies that the variation of the moment with stoichiometry in these materials is not governed by the filling of rigid transition-metal bands.