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The Highly Frustrated 5d2 Double Perovskite...
Journal article

The Highly Frustrated 5d2 Double Perovskite Doppelgängers, SrLaMgReO6 and SrLaLiOsO6. A Comparison including Isostructural La2LiReO6

Abstract

The synthesis and characterization of the double perovskite SrLaLiOsO6 is presented. It is isostructural (P21/n) and isoelectronic (5d2) with SrLaMgReO6, which has been reported previously. The cell volumes are the same to within 1.4%: i.e., these perovskites are doppelgängers. In a previous study SrLaMgReO6 showed no sign of spin order to 2 K. New data at lower temperatures disclose a maximum in the dc susceptibility near 1.5 K. As the …

Authors

Yuan F; Cronkwright ZW; Lussier JA; Wiebe CR; Dube PA; Thompson CM; Munsie TJS; Luke GM; Greedan JE

Journal

Inorganic Chemistry, Vol. 60, No. 21, pp. 16652–16657

Publisher

American Chemical Society (ACS)

Publication Date

November 1, 2021

DOI

10.1021/acs.inorgchem.1c02521

ISSN

0020-1669