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Stereochemical non-rigidity of the indenyl ligand...
Journal article

Stereochemical non-rigidity of the indenyl ligand in the compound [CrRh(µ-CO) 2 (CO) 2 ( η -C 9 H 7 )( η -C 6 H 3 Me 3 -1,3,5)]

Abstract

Examination of the variable temperature 13C-{1H} data for the compound [CrRh(µ-CO)2(CO)2-(η-C9H7)(η-C6H3Me3-1,3,5)] reveals dynamic behaviour involving hindered rotation of the η-C9H7 ligand; with ΔG‡ at –32 °C, 45.2 ± 1 kJ mol–1.

Authors

Barr RD; Green M; Marder TB; Stone FGA

Journal

Dalton Transactions, Vol. 0, No. 6, pp. 1261–1263

Publisher

Royal Society of Chemistry (RSC)

Publication Date

1984

DOI

10.1039/dt9840001261

ISSN

1477-9226