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Stable Hydrogen Storage Cycling in Magnesium...
Journal article

Stable Hydrogen Storage Cycling in Magnesium Hydride, in the Range of Room Temperature to 300 °C, Achieved Using a New Bimetallic Cr-V Nanoscale Catalyst

Abstract

We created a bimetallic chromium vanadium hydrogen sorption catalyst for magnesium hydride (MgH2). The catalyst allows for significant room-temperature hydrogen uptake, over 10 cycles, at absorption pressures as low as 2 bar. This is something that has never been previously achieved. The catalyst also allowed for ultrarapid and kinetically stable hydrogenation cycling (over 225 cycles) at 200 and at 300 °C. Transmission electron microscopy …

Authors

Zahiri B; Danaie M; Tan X; Amirkhiz BS; Botton GA; Mitlin D

Journal

The Journal of Physical Chemistry C, Vol. 116, No. 4, pp. 3188–3199

Publisher

American Chemical Society (ACS)

Publication Date

February 2, 2012

DOI

10.1021/jp211254k

ISSN

1932-7447