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Tracking and understanding the first-order...
Journal article

Tracking and understanding the first-order structural transition in Er5Si4

Abstract

Temperature-dependent single crystal x-ray-diffraction studies revealed a reversible first-order phase transition in Er5Si4. The high-temperature phase adopts the orthorhombic Gd5Si4-type structure, and the low-temperature phase has the monoclinic Gd5Si2Ge2-type structure. Unlike the magnetic/martensitic transition in Gd5Si2Ge2, the structural change in Er5Si4 is not coupled with a magnetic transition, and the structural sequence below room …

Authors

Mozharivskyj Y; Pecharsky AO; Pecharsky VK; Miller GJ; Gschneidner KA

Journal

Physical Review B, Vol. 69, No. 14,

Publisher

American Physical Society (APS)

Publication Date

April 1, 2004

DOI

10.1103/physrevb.69.144102

ISSN

2469-9950