Journal article
REACTIONS OF IMINO RADICALS WITH HYDROCARBON GASES
Abstract
The photolysis of HNCO vapor has been studied in the presence of ethylene, butene, ethane, propane, and neopentane at 51 °C. Both the olefins and paraffins reduced the yield of CO to about one-third of its value in pure HNCO, which is thought to correspond to the CO formed in the primary photolytic step. Yields of N 2 and H 2 were reduced close to zero in the presence of olefins, and it appears that NH radicals were removed by reaction with …
Authors
Brash JL; Back RA
Journal
Canadian Journal of Chemistry, Vol. 43, No. 6, pp. 1778–1783
Publisher
Canadian Science Publishing
Publication Date
June 1, 1965
DOI
10.1139/v65-234
ISSN
0008-4042