Journal article
Empirical bond-strength–bond-length curves for oxides
Abstract
Bond-strength-bond-length relationships for bonds between oxygen and H+, Li+, Be2+, B3+, Na+, Mg2+, Al3+, Si4+, P5+, S6+, K+, Ca2+, Sc3+, Ti4+, V5+, Cr6+, Mn2+, Fe3+, Fe2+, Co2+, Cu2+, Zn2+, Ga3+, Ge4+ and As5+ have been derived by requiring that the sums of the bond strengths around the cations be equal to their valence in 417 crystals whose structures have been accurately determined. The relationship is of the form s = (R/R0)-N where s = bond …
Authors
Brown ID; Shannon RD
Journal
Acta Crystallographica Section A: Foundations and advances, Vol. 29, No. 3, pp. 266–282
Publisher
International Union of Crystallography (IUCr)
Publication Date
May 1, 1973
DOI
10.1107/s0567739473000689
ISSN
0108-7673