Crystal structure of langbeinite-related Rb0.743K0.845Co0.293Ti1.707(PO4)3 Academic Article uri icon

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abstract

  • Potassium rubidium cobalt(II)/titanium(IV) tris(orthophosphate), Rb0.743K0.845Co0.293Ti1.707(PO4)3, has been obtained using a high-temperature crystallization method. The obtained compound has a langbeinite-type structure. The three-dimensional framework is built up from mixed-occupied (Co/TiIV)O6octahedra (point group symmetry .3.) and PO4tetrahedra. The K+and Rb+cations are statistically distributed over two distinct sites (both with site symmetry .3.) in the large cavities of the framework. They are surrounded by 12 O atoms.

authors

  • Brown, Ian David
  • Strutynska, Nataliia Yu
  • Bondarenko, Marina A
  • Ogorodnyk, Ivan V
  • Baumer, Vyacheslav N
  • Slobodyanik, Nikolay S

publication date

  • March 1, 2015