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Synthesis of fluorinated allenes using atomic...
Journal article

Synthesis of fluorinated allenes using atomic carbon

Abstract

Carbon vapour generated with a carbon arc reacts with CF2:CFX (X = CF3, Cl, or Br) to give the fluoro-allenes (X)(F)C:C:CF2. The products are rationalised in terms of cyclopropylcarbene intermediates.

Authors

McGlinchey MJ; Reynoldson T; Stone FGA

Journal

Journal of the Chemical Society D Chemical Communications, Vol. 0, No. 19, pp. 1264–1264

Publisher

Royal Society of Chemistry (RSC)

Publication Date

1970

DOI

10.1039/c29700001264

ISSN

0577-6171