Thioalcohols as bridging ligands in polynuclear PrIII/CuII and BaII/CuII complexes. Syntheses, structures and magnetic properties of Pr2Cu4(tde)3(Htde)2(hfacac) 4(μ6-O), Ba2Cu2(Htde)2(hfacac)4 and Cu4(tde) ...

Title full: Thioalcohols as bridging ligands in polynuclear Pr^III/Cu^II and Ba^II/Cu^II complexes. Syntheses, structures and magnetic properties of Pr2Cu4(tde)3(Htde)2(hfacac) ⁴(μ6-O), Ba2Cu2(Htde)2(hfacac)4 and Cu4(tde)2(hfacac)4, (H2tde = HOCH2CH2SCH2CH2OH). The syntheses of heterometallic compounds involving praseodymium, barium and copper ions by using 2,2′-thiodiethanol (H2tde) as the bridging ligand have been investigated. Three new …