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A linkage between the activity and the chemical...
Journal article

A linkage between the activity and the chemical potential

Abstract

A minimisation of an appropriate characteristic function (such as the Gibbs energy) of a system resulting in establishing its equilibrium state does not require a notion of component's activity, which, in contrast to the chemical potential, is nothing more than a helpful auxiliary entity bounded by finite limits. Also, the minimisation procedure does not impose rules on how a reference state for each component should be chosen, because the …

Authors

Malakhov DV

Journal

Canadian Metallurgical Quarterly, Vol. 59, No. 1, pp. 36–40

Publisher

Taylor & Francis

Publication Date

January 2, 2020

DOI

10.1080/00084433.2019.1630213

ISSN

0008-4433