Journal article
Macrocyclic complexes of Pt( ii ) and Rh( iii ) with iso-tellurazole N -oxides
Abstract
Pt(ii) and Rh(iii) readily form complexes with 3-methyl-5-aryl-1,2-tellurazole 2-oxides (L = (3-Me-5-Ar-1,2-C3HTe(NO)). The aryl group is either phenyl or 3,5-di-tert-butylphenyl, the latter case being a new derivative with enhanced solubility. The compound [Pt(3-Me-5-(3,5-tBu2C6H3)-1,2-C3HTe(NO))4](BF4)2 crystallizes in the P21/C space group featuring a square planar complex in the lattice. The crystal of …
Authors
Ho PC; Bui R; Cevallos A; Sequeira S; Britten JF; Vargas-Baca I
Journal
Dalton Transactions, Vol. 48, No. 15, pp. 4879–4886
Publisher
Royal Society of Chemistry (RSC)
Publication Date
April 9, 2019
DOI
10.1039/c9dt00500e
ISSN
1477-9226