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Journal article

trans-Dichloro(dimethyl sulfide-κS)(pyridine-κN)platinum(II)

Abstract

The structure of the title compound, [PtCl(2)(C(5)H(5)N)(C(2)H(6)S)], consists of discrete molecules in which the Pt-atom coordination is slightly distorted square planar. The Cl atoms are trans to each other, with a Cl-Pt-Cl angle of 176.60 (7) degrees. The pyridine ligand is rotated 64.5 (2) degrees from the Pt square plane and one of the Pt-Cl bonds essentially bisects the C-S-C angle of the dimethyl sulfide ligand. In the crystal structure, …

Authors

Burrow RA; Facco JT; Lang ES; Farrar DH; Lough AJ

Journal

Acta Crystallographica Section C: Structural Chemistry, Vol. 60, No. 1, pp. m7–m9

Publisher

International Union of Crystallography (IUCr)

Publication Date

January 15, 2004

DOI

10.1107/s0108270103026465

ISSN

0108-2701

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