Journal article
Reactions of carbon disulphide with palladium(0) complexes
Abstract
The reaction of PdLn (n = 3, L = PtBuPh2; n = 2, L = PtBu2Ph, PtBu3, PCy3) with CS2 in hexanes results in precipitation of either Pd(η2-CS2)L2 (L = PtBuPh2, PCy3) or Pd2(μ-CS2)2L2 (L = PtBu2Ph, PtBu3). The monomeric complexes Pd(CS2)L2 are unstable in a CS2 solution and convert to the corresponding doubly CS2-bridged dimeric complexes Pd2(CS2)2L2. It is the steric bulk of the phosphine ligands that appears to control which type of product …
Authors
Farrar DH; Gukathasan RR; Won K
Journal
Journal of Organometallic Chemistry, Vol. 275, No. 2, pp. 263–271
Publisher
Elsevier
Publication Date
October 1984
DOI
10.1016/0022-328x(84)85061-5
ISSN
0022-328X