The updated Zn–Sb phase diagram. How to make pure Zn₁₃Sb₁₀(“Zn₄Sb₃”). Journal Articles

The Zn–Sb system contains two well-known thermoelectric materials, Zn_1−δSb and Zn_13−δSb₁₀(“Zn₄Sb₃”), and two other phases, Zn_9−δSb₇and Zn_3−δSb₂, stable only at high temperatures.